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Ladder polymers for photonic applications
5. Carbazole-based copolymers
5.2.1 Poly[N-octylcarbazole-2,7-diyl-alt-2,1,3-benzothiadia
4.4.1 Low temperature fluorescence of LPPPC 52
5. Carbazole-based copolymers 58
6. Summary and Outlook 64
1. Introduction to conjugated polymers
History of conjugated polymers
1.2 Applications of conjugated polymers
1.3 Electroluminescent polymers
2 History and synthesis of ladder polymers
Figure 2.1: Arylene-type ladder polymers
3. Electrophosphorescence in a novel ladder type poly(para-
4. Carbazole containing polymers
4.3.4 Synthesis of ladder-type poly(para-phenylene-3,6-carb
4.4.1 Low temperature fluorescence of LPPPC
5. Carbazole-based copolymers
5.2.1 Poly[N-octylcarbazole-2,7-diyl-alt-2,1,3-benzothiadia
6. Summary and Outlook
Step 1: Preparation of Grignard Reagent
Yield: 550 mg (68.1 %)
GPC (THF): = 8,500 g/mol; = 16,800 g/mol; D = 1.97
GPC (THF): = 10,700 g/mol; = 15,100 g/mol; D = 1.41
Palladium content : 80 ppm
Yield: 750 mg (79.9 %)
GPC (THF): = 6,800 g/mol; = 10,800 g/mol; D = 1.58
Synthesis of alternating copolymers
7.7.1 Poly[N-octylcarbazole-2,7-diyl-alt-2,1,3-benzothiadiaz
GPC (THF): = 2,400 g/mol; = 2,900 g/mol; D = 1.21
GPC (THF): = 2,000 g/mol; = 2,500 g/mol D = 1.25
8. References
Dissertation
Ladder polymers for photonic applications / Satish Amrutrao Patil
Entstehung
2004
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