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Ladder polymers for photonic applications
1. Introduction to conjugated polymers
History of conjugated polymers
1.2 Applications of conjugated polymers
1.3 Electroluminescent polymers
4.4.1 Low temperature fluorescence of LPPPC 52
5. Carbazole-based copolymers 58
6. Summary and Outlook 64
1. Introduction to conjugated polymers
History of conjugated polymers
1.2 Applications of conjugated polymers
1.3 Electroluminescent polymers
2 History and synthesis of ladder polymers
Figure 2.1: Arylene-type ladder polymers
3. Electrophosphorescence in a novel ladder type poly(para-
4. Carbazole containing polymers
4.3.4 Synthesis of ladder-type poly(para-phenylene-3,6-carb
4.4.1 Low temperature fluorescence of LPPPC
5. Carbazole-based copolymers
5.2.1 Poly[N-octylcarbazole-2,7-diyl-alt-2,1,3-benzothiadia
6. Summary and Outlook
Step 1: Preparation of Grignard Reagent
Yield: 550 mg (68.1 %)
GPC (THF): = 8,500 g/mol; = 16,800 g/mol; D = 1.97
GPC (THF): = 10,700 g/mol; = 15,100 g/mol; D = 1.41
Palladium content : 80 ppm
Yield: 750 mg (79.9 %)
GPC (THF): = 6,800 g/mol; = 10,800 g/mol; D = 1.58
Synthesis of alternating copolymers
7.7.1 Poly[N-octylcarbazole-2,7-diyl-alt-2,1,3-benzothiadiaz
GPC (THF): = 2,400 g/mol; = 2,900 g/mol; D = 1.21
GPC (THF): = 2,000 g/mol; = 2,500 g/mol D = 1.25
8. References
Dissertation
Ladder polymers for photonic applications / Satish Amrutrao Patil
Entstehung
2004
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