Kinetic and product studies of the hydroxyl radical initiated oxidation of dimethyl sulfide in the temperature range 250 - 300 K / submitted by Mihaela Albu. 2008
Content
Chapter 1
Chapter 2
Chapter 3
Experimental section
3.1 Experimental set-up
3.1.1 Description of the reaction chamber
3.1.2 Description of the sampling system for ion chromatography analysis
3.2 Typical experimental procedure
3.2.1 Kinetic experiments on the system DMS ( OH radicals
3.2.2 Product study experiments on the system DMS ( OH radicals
3.3 Generation of OH radicals
3.4 Data analysis
Chapter 4
Chapter 5
Product study of the OH radical initiated oxidation of dimethyl sulfide
5.1 Experimental results
5.1.1 Dimethyl sulfoxide (DMSO)
5.1.2 Dimethyl sulfone (DMSO2)
5.1.3 Sulfur dioxide (SO2)
5.1.4 Methyl sulfonyl peroxynitrate (MSPN)
5.1.5 Methyl thiol formate (MTF)
5.1.6 Carbonyl sulfide (OCS)
5.1.7. Methane sulfonic acid (MSA) and methane sulfinic acid (MSIA)
5.2 Discussion of the results and comparison with literature data
5.2.1 Dimethyl sulfoxide (DMSO) and dimethyl sulfone (DMSO2) formation
5.2.2 Sulfur dioxide (SO2), methyl thiol formate (MTF), methane sulfonic acid (MSA) and methyl sulfonyl peroxynitrate (MSPN) formation
5.2.3 Carbonyl sulfide (OCS) formation
5.2.4 Methane sulfonic acid (MSA) and methane sulfinic acid (MSIA) formation
5.3 Summary of the product results
Chapter 6
Summary
Appendix I
Appendix II
Appendix III
Appendix IV
Appendix V
References