Kinetic and product studies of the hydroxyl radical initiated oxidation of dimethyl sulfide in the temperature range 250 - 300 K / submitted by Mihaela Albu. 2008
Inhalt
- Chapter 1
- Chapter 2
- Chapter 3
- Experimental section
- 3.1 Experimental set-up
- 3.1.1 Description of the reaction chamber
- 3.1.2 Description of the sampling system for ion chromatography analysis
- 3.2 Typical experimental procedure
- 3.2.1 Kinetic experiments on the system DMS ( OH radicals
- 3.2.2 Product study experiments on the system DMS ( OH radicals
- 3.3 Generation of OH radicals
- 3.4 Data analysis
- Chapter 4
- Chapter 5
- Product study of the OH radical initiated oxidation of dimethyl sulfide
- 5.1 Experimental results
- 5.1.1 Dimethyl sulfoxide (DMSO)
- 5.1.2 Dimethyl sulfone (DMSO2)
- 5.1.3 Sulfur dioxide (SO2)
- 5.1.4 Methyl sulfonyl peroxynitrate (MSPN)
- 5.1.5 Methyl thiol formate (MTF)
- 5.1.6 Carbonyl sulfide (OCS)
- 5.1.7. Methane sulfonic acid (MSA) and methane sulfinic acid (MSIA)
- 5.2 Discussion of the results and comparison with literature data
- 5.2.1 Dimethyl sulfoxide (DMSO) and dimethyl sulfone (DMSO2) formation
- 5.2.2 Sulfur dioxide (SO2), methyl thiol formate (MTF), methane sulfonic acid (MSA) and methyl sulfonyl peroxynitrate (MSPN) formation
- 5.2.3 Carbonyl sulfide (OCS) formation
- 5.2.4 Methane sulfonic acid (MSA) and methane sulfinic acid (MSIA) formation
- 5.3 Summary of the product results
- Chapter 6
- Summary
- Appendix I
- Appendix II
- Appendix III
- Appendix IV
- Appendix V
- References