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Functional layers and interfaces for perovskite single- and multi-junction solar cells / Kai Oliver Brinkmann. Wuppertal, [2022]
Inhalt
1 Introduction
2 Basics
2.1 Introduction of Perovskites
2.2 Perovskite Material Properties
2.2.1 Electronic, Optical and Structural Properties
2.2.2 Layer Formation / Crystallization
2.2.3 Degradation Mechanisms
2.3 Perovskite Solar Cell Application
2.3.1 Charge Extraction
2.3.2 Open Circuit Voltage vs. Recombination
2.3.3 J-V Hysteresis
2.4 Brief Digression on Organic Solar Cells
2.4.1 Transport and Exciton Splitting in Organic Semiconductors
2.4.2 Non-Fullerene Acceptors
2.5 Multi-Junction Solar Cells
2.5.1 Shockley Queisser - Limit of Single Junctions
2.5.2 Prospects and Challenges of Tandem Cells
3 Formation of Perovskite Layers
3.1 Perovskite Deposition Techniques
3.2 Perovskite Layer Formation and Precursor Chemistry
3.2.1 Solvent Removal Speed and Contact Angle
3.2.2 Lead Complexes in Perovskite Precursors
3.3 Gas Quenching on Hydrophobic Surfaces
3.3.1 Origin of Precursor De-Wetting and How to Overcome it
3.3.2 Highly Reproducible Perovskite Solar Cells
4 Stability of Perovskite Solar Cells
4.1 Manipulating the Air Stability by Internal ALD Barriers
4.2 Suppressed Thermal Decomposition by ALD Barriers
4.3 Combined Thermal and Illumination Stress
5 Hybrid Metal Oxide Barrier Layers
5.1 Hybrid Metal Oxide Layers Grown by Batch or Spatial ALD
6 Semi-Transparent Cells with Hybrid Metal Oxide Layers
6.1 Sandwiched Ultra-Thin Silver Layers
6.2 Water Processed Silver Nanowire Top Electrodes
7 Interfaces of Wide Gap Perovskite Solar Cells
7.1 Top- and Bottom-Side Interface Optimization
7.2 Optical Origin of External Quantum Efficiencies Near Unity
8 Perovskite-Organic Tandem Solar Cells
8.1 Organic Sub-Cell Stability under Tandem Conditions
8.2 Metal-like Indium Oxide as Universal Interconnect
8.3 Highly Efficient Tandem Cells
9 Conclusion and Outlook
10 Publications and Conference Contributions
11 Appendix